The carbonyl methylene condensation reaction of aromatic aldehydes with ethyl cyanoacetate has been carried out smoothly in the presence of potassium fluoride only giving E isomers in high yield. 在氟化钾催化下,芳香醛与氰乙酸乙酯发生羰基与活性亚甲基的缩合反应,高收率地得到缩合产物,且只得到E式产物。
Four active cyclopropane compounds 2a-2d were synthesized using active methylene ( 1a-1d) and 1, 2-dibromoethane with potassium fluoride soaking alumina as a strong base under the condition of solid-liquid phase transfer catalysis, and the reaction mechanism was discussed in this paper. 以氟化钾浸渍的氧化铝为强碱,在固液相转移催化条件下,由活泼亚甲基化合物(1a~1d)与1,2-二溴乙烷合成了4种活性环丙烷化合物2a~2d,并探讨了其反应机理。
Electron Momentum Spectroscopy of Inner Valence Orbitals 3a_1 and 2b_2 of Methylene Fluoride 二氟甲烷分子3a1和2b2轨道的电子动量谱